Antimicrobial properties of highly fluorinated silver(I) tris(pyrazolyl)borates |
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Authors: | Dias H V Rasika Batdorf Keith H Fianchini Mauro Diyabalanage Himashinie V K Carnahan Sean Mulcahy Ryan Rabiee Amir Nelson Kevin van Waasbergen Lorraine G |
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Affiliation: | Department of Chemistry and Biochemistry, The University of Texas at Arlington, P.O. Box 19065, Arlington, TX 76019, USA. dias@uta.edu |
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Abstract: | Highly fluorinated tris(pyrazolyl)borate ligand [HB(3,5-(CF3)2Pz)3]- has been used in the isolation of air- and light-stable silver complex, [HB(3,5-(CF3)2Pz)3]Ag(OSMe2). It is a monomeric tetrahedral silver complex with an O-bonded dimethylsulfoxide ligand. The silver adduct [HB(3,5-(CF3)2Pz)3]Ag(OSMe2) and the related [HB(3,5-(CF3)2Pz)3] Ag(THF) (where OSMe2 = dimethyl sulfoxide; THF = tetrahydrofuran) show good antibacterial activity, and their antimicrobial efficacy against Staphylococcus aureus is greater than those of AgNO3 and silver sulfadiazine. |
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