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Essential Oil Composition of Three Globularia Species
Authors:Maja Crkvenčić  Slavica Dudaš  Igor Jerković  Zvonimir Marijanović  Danijela Poljuha  Kroata Hazler Pilepić
Affiliation:1. Department of Pharmaceutical Botany, Faculty of Pharmacy and Biochemistry, University of Zagreb, Schrottova 39, HR‐10000 Zagreb (phone: +385‐1‐4622896;2. fax: +385‐1‐4622895);3. Agricultural Department, Polytechnic of Rijeka, Karla Huguesa 6, HR‐52440 Pore?;4. Department of Organic Chemistry, Faculty of Chemistry and Technology, University of Split, N. Tesle 10/V, HR‐21000 Split;5. ‘Marko Maruli?' Polytechnic of Knin, P. Kre?imira IV 30, HR‐22300 Knin;6. Department of Agriculture and Nutrition, Institute of Agriculture and Tourism, Karla Huguesa 8, HR‐52440 Pore?
Abstract:The chemical composition of the essential oils obtained by hydrodistillation from the aerial parts of Globularia cordifolia L., G. meridionalis (Podp.) O.Schwarz , and G. punctata Lapeyr . was characterized by GC‐FID and GC/MS analyses. Among the 33 identified compounds, the most abundant present in all investigated samples were oct‐1‐en‐3‐ol (2.9–47.0%), 6‐(1,5‐dimethylhex‐4‐enyl)‐3‐methylcyclohex‐2‐enone (8.2–40.9%), and fukinanolid (7.4–31.6%). Multivariate statistical analyses (PCA and HCA) of the hitherto studied Globularia volatile compounds confirmed to some extent the assumed phylogenetic relationships of the Globularia species studied, including the close relationship between the morphologically similar species G. cordifolia and G. meridionalis, but also evidenced several discrepancies in the current classification of Globularia species.
Keywords:Globularia cordifolia  Globularia meridionalis  Globularia punctata  Essential oils  Chemotaxonomy  Principal component analysis (PCA)  Hierarchical cluster analysis (HCA)
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