Synthesis of annonaceous acetogenins from muricatacin |
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| Authors: | Makabe Hidefumi |
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| Institution: | Sciences of Functional Foods, Graduate School of Agriculture, Shinshu University, Japan. makabeh@shinshu-u.ac.jp |
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| Abstract: | Synthetic studies of annonaceous acetogenins starting from (-)-muricatacin (1a) or (+)-muricatacin are described, involving (-)-muricatacin (1a), mono-THF acetogenin, solamin (2), reticulatacin (3), (15R, 16R, 19S, 20S)-cis-solamin (4a) and (15S, 16S, 19R, 20R)-cis-solamin (4b), non-adjacent bis-THF acetogenin, 4-deoxygigantecin (5), and epoxide-bearing acetogenin, (15S, 16R, 19S, 20R)-diepomuricanin (6a). |
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