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Sesquiterpene constituents from the essential oil of the liverwort Plagiochila asplenioides
Authors:Adio Adewale Martins  König Wilfried A
Affiliation:Institut für Organische Chemie, Universit?t Hamburg, Martin-Luther-King-Platz 6, D-20146 Hamburg, Germany. adio20002000@yahoo.com
Abstract:The essential oil of the liverwort Plagiochila asplenioides from two different locations in Northern Germany were investigated by chromatographic and spectroscopic methods. Seven compounds were isolated by preparative gas chromatography (GC) and their structures investigated by mass spectrometry (MS), NMR techniques and chemical correlations in combination with enantioselective GC. In addition to known constituents, aromadendra-1(10),3-diene, two aromatic sesquiterpene hydrocarbons, bisabola-1,3,5,7(14)-tetraene and bisabola-1,3,5,7-tetraene, three sesquiterpene ethers, muurolan-4,7-peroxide, plagiochilines W and X, in addition to ent-4-epi-maaliol, could be identified as natural compounds for the first time.
Keywords:Plagiochila asplenioides   Liverworts   Sesquiterpene hydrocarbons   Oxygenated sesquiterpenes   abeo-Amorphane/muurolane   seco-Aromadendrane-type sesquiterpenoids
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