|
|||||
|
|
A ferrocene-perfluoroarene molecular complex |
|
| Authors: | Christopher M Beck Juan Burdeniuc Robert H Crabtree Arnold L Rheingold Glenn PA Yap |
| Institution: | aDepartment of Chemistry, Yale University, New Haven, CT 06520, USA bDepartment of Chemistry, University of Delaware, Newark, DE 19716, USA |
| Abstract: | Perfluorophenanthrene and decamethylferrocene cocrystallize as a molecular adduct in monoclinic space group P21/c with a = 8.842(2), b = 11.262(1), c = 30.695(8) A?, β = 95.89(2)°, V = 3040.3(8) A?3, Z = 4. The structure was refined to R = 0.0537 for 1567 observed reflections. The perfluoroarene is twisted and chiral; the crystal is a racemate, however. |
| Keywords: | Crystal structures Ferrocene complexes Perfluoroarene complexes |
| 本文献已被 ScienceDirect 等数据库收录！ | |