Preparation and characterization of some Cr(III) chloro-complexes with nicotinic acid esters |
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Authors: | J. Barrett,M.K. Kormoh,P. O Brien |
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Affiliation: | Department of Chemistry, Chelsea College, Manresa Road, Chelsea, London SW3 6LX, U.K. |
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Abstract: | The preparation and characterisation of the trichlorotris(alkylnicotinate)chromium(III) complexes of general formula CrCl3(py·3COOR)3·nH2O, where R = Me, Et, Pr and Bu are reported, n being 3.5, 1.0, 0 and 0 respectively. It is concluded that the ligation of the three chloride ions and that of the three nitrogen atoms is consistent with a C2u arrangement in each case. |
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Keywords: | Authors to whom correspondence should be addressed. |
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