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Preparation and characterization of some Cr(III) chloro-complexes with nicotinic acid esters
Authors:J. Barrett,M.K. Kormoh,P. O&#x  Brien
Affiliation:Department of Chemistry, Chelsea College, Manresa Road, Chelsea, London SW3 6LX, U.K.
Abstract:The preparation and characterisation of the trichlorotris(alkylnicotinate)chromium(III) complexes of general formula CrCl3(py·3COOR)3·nH2O, where R = Me, Et, Pr and Bu are reported, n being 3.5, 1.0, 0 and 0 respectively. It is concluded that the ligation of the three chloride ions and that of the three nitrogen atoms is consistent with a C2u arrangement in each case.
Keywords:Authors to whom correspondence should be addressed.
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