Fe(NTA)-catalyzed dioxygenation of 4-t-butylcatechol and the mechanism of non-heme ferric dioxygenases |
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| Authors: | Michael G Weller Ulrich Weser |
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| Institution: | Anorganische Biochemie, Physiologisch-chemisches Institut der Universität Tübingen, Hoppe-Seyler-Str. 1, D-7400 Tübingen, F.R.G. |
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| Abstract: | Fe(NTA), activating the ‘substrate’ 4-t-butyl- catechole, represents a functional active centre analogue of non-heme ferric dioxygenases. A Fe(NTA) catecholate complex with monodentate catecholate is the reactive species to undergo dioxygenation. |
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