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Conversion of Farnesol into Methyl dl-12-Homo-10-trans-juvenate,the 10-trans-lsomer of dl-C17-Cecropia Juvenile Hormone
Authors:Kenji Mori
Affiliation:Department of Agricultural Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo, 113
Abstract:Methyl dl-12-homo-10-trans-juvenate (III) was synthesized from farnesol (IV) in eight steps involving stereoselective conversion of the trans-terminal methyl group to an ethyl group. The product (III) was less active than dl-C17-Cecropia juvenile hormone on both Tenebrio molitor and Galleria mellonella.
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