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Studies on Organic Insecticides
Authors:Kazuo Konishi
Affiliation:Agricultural Chemicals Division, Takeda Chemical Industries, Ltd., Juso, Osaka
Abstract:An improved synthesis of nereistoxin, 4-dimethylamino-1, 2-dithiolane (Ia), has been achieved in a 3-step sequence starting from 1, 3-bis (benzylthio)-2-propanone (IIa) or 2-phenyl-1, 3-dithian-5-one (IVa). By the similar route 4-amino-1, 2-dithiolane (Ib), 4-methylamino-1, 2-dithiolane (Ic) and two S-acyl derivatives (VIa, b) of dihydronereistoxin were synthesized and their insecticidal activities were tested.
Keywords:
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