Configurational Relationship between Substituents on Cyclopropane Ring of Pyrethroids and Their Insecticidal Toxicity |
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Authors: | Takeyoshi Sugiyama Akio Kobayashi Kyohei Yamashita |
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Institution: | Department of Agricultural Chemistry, Faculty of Agriculture, Tohoku University, Sendai, Japan |
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Abstract: | Several methyl-substituted cyclopropanecarboxylates were prepared and their steric configurations were established. The insecticidal activity against the housefly of their 5-benzyl-3-furylmethyl esters were tested. Among the substituents on cyclopropane ring, cis-methyl group to ester linkage has been found to be the most essential part for toxicity and trans-methyl and trans-isobutenyl groups greatly enhance its toxic activity. |
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Keywords: | coumarins anisumarin Rutaceae Clausena anisum-olens Merr |
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