Studies on Lignin |
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Authors: | Tatsuo Ishihara Tamio Kondo |
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Affiliation: | 1. Government Forest Experiment Station, Meguro, Tokyo;2. Faculty of Agriculture, Kyushu University, Fukuoka |
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Abstract: | In comparison with the ethanolysis, the mercaptolysis of pine wood and pine ethanol lignin has been studied. The delignification was found to be almost complete when wood powder was cooked with the ethanolic hydrogen chloride containing 10% of ethyl mercaptan; while the same cooking without the mercaptan caused only 50% of delignification. Addition of 2% of mercaptan resulted more than 90% of delignification. As already reported briefly, from the mercaptolysis oil of pine ethanol lignin, 2-ethoxy-1-(4-hydroxy-3-methoxyphenyl)-propanone- (1), a thioether corresponding to Hibbert’s α-ethoxypropiovanillone, was isolated. |
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