Dehydrocostuslactone and plant growth activity of derived guaianolides |
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Authors: | S Kalsi Gurdeep Kaur Sunila Sharma KK Talwar |
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Institution: | Department of Chemistry, Punjab Agricultural University, Ludhiana, India |
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Abstract: | The stereostructures of two new guaianolides, isodehydrocostuslactone and isozaluzanin C, isolated previously from Saussurea lappa, have been confirmed by their correlation with dehydrocostuslactone. Twenty new derivatives have been synthesized from these guaianolides and these have been tested as plant growth regulators. The conjugated lactones which have an exocyclic methylene group at C-4 conjugated with a C-3 ketone, show distinct enhancement in their root-forming potential, as compared with their 3-deoxy derivatives. Of further significance is the fact that these ketones display maximum activity only at lower concentrations. Other compounds show the expected structure-biological activity relationships displayed in general by guaianolides. However, the presence of an epoxide at the C-3, C-4 position does not affect the biological activity, which is indeed the case when the epoxide group occupies the C-4, C-14 position in guaianolides. The major biological parameter studied was rooting in-stem cuttings of Phaseolus aureus. |
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Keywords: | Compositae root promoters sesquiterpene lactone guaianolide dehydrocostuslactone estafiatin isozaluzanin C isodehydrocostuslactone |
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