Fatty acids,part 54. Some reactions of long-chain oxygenated acids with special reference to those furnishing furanoid acids |
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Authors: | FD Gunstone RC Wijesundera |
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Institution: | Department of Chemistry, The Purdie Building, The University of St. Andrews, Scotland, KY16 9ST United Kingdom |
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Abstract: | C18 furanoid acids are prepared from natural oxygenated acids by palladium (II)-catalysed cyclodehydrogenation, by rearrangement of epoxides with iodopropane-sodium iodide-dimethylsulphoxide, and by dehydration of endoperoxides. Some reactions give mixed products but routes to the individual 10,13-, 9,12- and 8,11-furans are reported. The endoperoxide route leads to speculation about the biosynthesis of natural furanoid acids. |
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