Preparation of α- and β-dienyl glycosides used as dienes in aqueous Diels-Alder reactions. Influence of the carbohydrate moiety on the thermodynamics of the reaction |
| |
| Authors: | Andr Lubineau, Hugues Bienaym ,Yves Queneau |
| |
| Affiliation: | André Lubineau, Hugues Bienaymé,Yves Queneau |
| |
| Abstract: | A series of 1,3-butadienyl glycosides (mono- and di-saccharides) have been prepared and the kinetics of their Diels-Alder reaction with buten-2-one in water have been studied. The activation parameters for these aqueous cycloadditions provide clues for the hydration structure of such glyco-organic compounds. |
| |
| Keywords: | Organic synthesis in water Cycloadditions Dienyl glycosides Kinetics Sugar hydration |
| 本文献已被 ScienceDirect 等数据库收录！ |
