Synthesis and absolute configuration of (-)-3-butyl-7-hydroxyphthalide, a cytotoxic metabolite of Penicillium vulpinum |
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| Authors: | Ohzeki Tomoya Mori Kenji |
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| Affiliation: | Department of Chemistry, Graduate School of Science, Science University of Tokyo, Kagurazaka, Tokyo, Japan. |
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| Abstract: | Both the enantiomers as well as the racemate of 3-butyl-7-hydroxyphthalide (1) were synthesized, and the absolute configuration of the naturally occurring (-)-1 (a weakly cytotoxic metabolite of Penicillium vulpinum) was identified as S. |
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