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Triterpenoid saponins from Echinopsis macrogona (Cactaceae)
Authors:Okazaki Sachie  Kinoshita Kaoru  Ito Satoru  Koyama Kiyotaka  Yuasa Hiroshi  Takahashi Kunio
Institution:a Department of Pharmacognosy and Phytochemistry, Meiji Pharmaceutical University, 2-522-1 Noshio, Kiyose-shi, Tokyo 204-8588, Japan
b Research Institute of Evolutionary Biology, 2-4-28 Kamiyoga, Setagaya-ku, Tokyo 158-0098, Japan
Abstract:Triterpene saponins, pachanosides C1, E1, F1 and G1 (1-4), and bridgesides A1, C1, C2, D1, D2, E1 and E2 (5-11) were isolated from Echinopsis macrogona. Compounds 1-4 were saponins with pachanane type triterpene saponins, while the others (5-11) were oleanane type triterpene saponins. While the aglycones of 2-4 and 8-11 were hitherto unknown, the structure of pachanol C was revised in this paper. Their structures were elucidated on the basis of chemical and physicochemical evidence.
Keywords:Echinopsis macrogona  Cactaceae  Saponins  Pachanane type  Pahanoside  Bridgeside
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