The cis-trans isomerization of aromatic heptaenes catalyzed by sulfur and phosphorus compounds] |
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Authors: | Iu D Shenin A I Filippova |
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Affiliation: | Research Technological Institute of Antibiotics and Medical Enzymes, St. Petersburg. |
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Abstract: | It was shown that sulfur and phosphorus compounds (sodium thiosulfate, sodium tripolyphosphate, sodium hexametaphosphate, monosodium phosphate) catalyze cis-trans isomerization of aromatic heptaens. Preparative method of levorin isomerezation at the presence of sodium thiosulfate was elaborated. The isolated product was a fully trans-isomer. |
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