neo-Clerodane diterpenoids from the leaf exudate of Dodonaea angustifolia |
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Authors: | Leonidah K. Omosa Jacob O. Midiwo Solomon Derese Abiy Yenesew Martin G. Peter Matthias Heydenreich |
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Affiliation: | 1. Department of Chemistry, University of Nairobi, Chiromo Lane, Chiromo Campus, P.O. Box 30197-00100, Nairobi, Kenya;2. Institut für Chemie, Universität Potsdam, P.O. Box 60 15 53, D-14415 Potsdam, Germany |
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Abstract: | Phytochemical investigation of the leaf surface exudate of Dodonaea angustifolia L.f. yielded two new neo-clerodane diterpenes, neo-clerodan-3,13-dien-16,15:18,19-diolide (mkapwanin) and 15-methoxy-neo-clerodan-3,13-dien-16,15:18,19-diolide (15-methoxymkapwanin). In addition, ten known compounds were identified. The structures were determined on the basis of spectroscopic evidence. This additional chemical information could contribute towards solving the taxonomical controversy that exists between Dodonaea angustifolia and Dodonaea viscosa Jacq., which are morphologically similar. |
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