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Utilization of acrylates emulsion terpolymer with chitosan as a finishing agent for cotton fabrics
Authors:HE Nasr  SM Sayyah  DM Essa  SH Samaha  AM Rabie
Institution:1. Polymers and Pigments Department, National Research Center, El Buhoth Street, Cairo, Dokki 12311, Egypt;2. Chemistry Department, Faculty of Science, Beni-Suef University, Beni-Suef, Egypt;3. Textile Metrology Department, National Institute for Standards, Tersa Street, Giza, Egypt;4. Chemistry Department-Faculty of Science, Ain Shams University, Cairo, Egypt
Abstract:Cotton fabrics were treated with finishing bath formulation containing emulsion lattices based on acrylate monomers, chitosan and polyethylene glycol (PEG) to provide cotton fabrics with antibacterial, UV-protection as well as improvement of dyeing properties with direct, acid and reactive dyes. The terpolymer emulsion, chitosan and PEG concentrations as well as fabric pretreatment with alkali significantly affected the performance properties, antimicrobial activity, UV-protection and dyeing behavior of treated cotton fabric. The finished fabrics were characterized in terms of FTIR, X-ray diffraction, scanning electron microscope (SEM) as well as mechanical properties such as tensile strength, elongation at break (%), abrasion resistance and air permeability. The obtained data showed that the tested fabrics have appropriate antibacterial activity with highly UV-protection properties with increasing chitosan concentration up to 3%. The mechanical properties expressed as tensile strength and abrasion resistance increased after finishing treatment. Moreover, the performance of the finished fabrics and dyeing properties with different dyes classes were greatly influenced by the action of alkali pretreatment of cotton fabrics, adding the polyethylene glycol to the finishing bath formulation as well as emulsion and chitosan concentrations.
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