Substituted polyaniline/chitosan composites: Synthesis and characterization |
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Authors: | Ayse Gul Yavuz Aysegul Uygun Venkat R. Bhethanabotla |
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Affiliation: | 1. Suleyman Demirel University, Arts and Science Faculty, Department of Chemistry, Suleyman Demirel Street, 32260 Isparta, Turkey;2. University of South Florida, Sensors Research Laboratory, Department of Chemical and Biomedical Engineering, Tampa, FL 33620-5350, USA |
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Abstract: | Substituted polyaniline/chitosan(PANIs/Ch) composites were chemically synthesized by using ammonium peroxydisulfate as oxidant and characterized by measurements of conductivity, FTIR, UV–vis, SEM and TGA techniques. FTIR spectra of the composites revealed that there is a strong interaction between substituted polyanilines and chitosan. Among the substituted polyaniline/chitosan composites synthesized, poly(N-ethylaniline)/chitosan PNEANI/Ch has the highest conductivity with a value of 1.68 × 10?4 S/cm. The P2EANI/Ch composite exhibited higher thermal stability than the other composites. SEM images of the composites showed an agglomerated granular morphology of substituted polyaniline particles coated on the surface of chitosan. |
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