Synthesis of 2(R),3-dihydroxypropyl and 2(R),3(R)-dihydroxybutyl beta-D-fructopyranosides and some derivatives |
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| Authors: | Sung'hwa Fortunatus Strik Axel Regeling Henk Zwanenburg Binne Chittenden Gordon J F |
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| Affiliation: | Department of Organic Chemistry, IMM Center, Radboud University Nijmegen, Toernooiveld 1, NL-6525 ED Nijmegen, The Netherlands |
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| Abstract: | The synthesis of 2(R),3-dihydroxypropyl and 2(R),3(R)-dihydroxybutyl β-d-fructopyranosides, and some derivatives, employing Sharpless-type catalytic asymmetric dihydroxylation procedures is described. Some aspects of the reactions, including stereoselectivities and chemical evidence for the assigned stereochemistry of the main products are reported. |
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| Keywords: | Alkenyl fructosides Dihydroxyalkyl fructosides Asymmetric dihydroxylations Fructosyl glycolipids |
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