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Lipase-mediated esterification of racemic alcohols: A comparison of 2-substituted cyclohexanols and cyclopentanols
Authors:Marie Zarevúcka  Martin Rejzek  Zdeněk Wimmer  Jan Zima  Qiu-yu Zhao  Marie-Dominique Legoy
Institution:(1) Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 6 Prague, Czech Republic;(2) University of La Rochelle, Avenue Marillac, F-17042 La Rochelle, France
Abstract:Summary Esterification of five- and six-membered-ring-containing alcohols catalysed by three different lipases (those from porcine pancreas, Candida cylindracea and Geotrichum candidum) was studied. Some conversions gave high stereochemical purity, but all gave low yields.
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