Lipase-mediated esterification of racemic alcohols: A comparison of 2-substituted cyclohexanols and cyclopentanols |
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Authors: | Marie Zarevúcka Martin Rejzek Zdeněk Wimmer Jan Zima Qiu-yu Zhao Marie-Dominique Legoy |
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Institution: | (1) Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 6 Prague, Czech Republic;(2) University of La Rochelle, Avenue Marillac, F-17042 La Rochelle, France |
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Abstract: | Summary Esterification of five- and six-membered-ring-containing alcohols catalysed by three different lipases (those from porcine pancreas, Candida cylindracea and Geotrichum candidum) was studied. Some conversions gave high stereochemical purity, but all gave low yields. |
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