Dinuclear nickel(II) and zinc(II) complexes of 2,6-bis[{bis(2-pyridylmethyl)amino}methyl]-4-methylphenol |
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| Authors: | Harry AdamsDarren Bradshaw David E Fenton |
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| Affiliation: | Department of Chemistry, Dainton Building, The University of Sheffield, Sheffield S3 7HF, UK |
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| Abstract: | Reaction of the symmetrical proligand H2L with metal(II) acetate and a counteranion to promote crystallisation has given the homodinuclear complexes [Zn2L(OAc)2](BF4)]·2MeOH and [Ni2L(OAc)2](BF4)]·2MeOH the crystal structures of which are reported. These show the presence of a triply bridging (μ-cresolato)bis(μ-carboxylato) dimetal core. |
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| Keywords: | Crystal structures Zinc(II) complexes Nickel(II) complexes |
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