On an erroneous view of fluxional behaviour of [Fe3(CO)12] |
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| Authors: | Brian FG Johnson Steven Tay |
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| Institution: | University Chemical Laboratory, Lensfield Road, Cambridge CB2 1 EW, UK |
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| Abstract: | The idea that the mechanism of the very low energy fluxional behaviour of Fe3(CO)12] may be based on the movement of the ligand icosahedron about the central Fe3 triangle which corresponds to a rotational symmetry operation of the CO ligand icosahedron is discussed and rejected. |
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| Keywords: | Ligand polyhedral model [Fe3(CO)12] Fluxionality |
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