Aggregation of imino-phosphonate monoester complexes |
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| Authors: | Dan M.J DobleAlexander J Blake,Paul A CookeSimon Parsons,Martin Schrö der |
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| Affiliation: | a School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK
b Department of Chemistry, University of Edinburgh, Kings Buildings, Edinburgh EH9 3JJ, UK |
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| Abstract: | The aggregates {[Zn(L1)]H2O}∞ and {[Y(L2)]4Na3(H2O)2(MeOH)1.2}(NO3)3·2H2O·5.6MeOH have been assembled from complexes of imino-phosphonate monoester ligands [L1]2− {CH2[CH2NC(CH3)PO2(OMe)]2}2− and [L2]3− {N[CH2CH2NC(CH3)PO2(OMe)]3}3−, the topology of these materials differing from that of their imino-carboxylate analogues. |
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| Keywords: | Crystal structures Zinc complexes Imino-phosphonate complexes Aggregation |
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