Solid state coordination chemistry: the hydrothermal synthesis and structure of a bimetallic oxide incorporating 2,2′:6′,2″-terpyridine (terpy), [{VO(terpy)}MoO4] |
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| Authors: | Robert C FinnJon Zubieta |
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| Institution: | Department of Chemistry, Syracuse University, Room 1-014, Syracuse, NY 13244-4100, USA |
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| Abstract: | The hydrothermal reaction of MoO3, Na3VO4, 2,2′:6′,2″-terpyridine (terpy) and H2O in the mole ratio 1.53:1.00:1.30:1460 at pH 3 yields red crystals of {VO(terpy)}MoO4] (1) in 55% yield. The structure of 1 is a one-dimensional chain of {VO(terpy)}2+ units bridged in the characteristic O,O′-mode by {MoO4}2− tetrahedra. Crystal data: C15H11N3O5MoV, orthorhombic, P212121, a=26.145(1) Å, b=6.7607(4) Å, c=9.2496(5) Å, V=1634.9(2) Å3, Z=2, Dcalc=1.869 g cm−3; structure solution and refinement converged at R1=0.0335 and wR2=0.0735. |
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| Keywords: | Vanadomolybdate structures Organic-inorganic hybrid materials Bimetallic oxide Hydrothermal synthesis Solid state coordination chemistry |
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