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An efficient synthesis of two monosulfated trisaccharides with the Galbeta1,3GlcNacbeta1,3Galbeta-O-allyl backbone
Authors:Xia J  Piskorz C F  Locke R D  Chandrasekaran E V  Alderfer J L  Matta K L
Institution:Department of Molecular & Cellular Biophysics, Roswell Park Cancer Institute, Buffalo, NY 14263, USA.
Abstract:The GlcNAcbeta(1-->3) Gal linked disaccharide 7 was synthesized as key building blocks for the construction of target monosulfated trisaccharides 1 and 2 using oxazoline 3 as glycosyl donor promoted by BF3 x Et2O.
Keywords:
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