An unexpected rearrangement giving a new thiosubstituted carbohydrate |
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| Authors: | Agathe Martinez |
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| Affiliation: | Institut de Chimie Moléculaire de Reims, UMR CNRS, Université de Reims, BP 1039, F-51687 REIMS Cedex, France |
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| Abstract: | A new thiosubstituted ‘d-arabino’-type derivative was obtained from an open carbohydrate via a cascade of four consecutive transformations in a single reaction process. Molecular orbital computations were also performed to explain the stereochemical outcome of the reaction. |
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| Keywords: | Thiosugars Theoretical Conformational bias DFT Transition state |
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