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Heterogeneous electron transfer of cytochrome c facilitated by polypyrrole and methylene blue polypyrrole film modified electrodes
Authors:W B Zhang  S H Song  S J Dong
Affiliation:Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Academia Sinica, Peoples Republic of China.
Abstract:Polypyrrole and methylene blue incorporated polypyrrole thin-film modified electrodes were prepared by the electrochemical polymerization method. These modified electrodes may facilitate heterogeneous electron transfer of cytochrome c with high electrocatalytic activity and good stability. Optical thin-layer spectroelectrochemical techniques were used to determine the characteristics of these electrochemical processes such as formal redox potential (E0), electron transfer number (n), and the apparent rate constant (ks.h0).
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