Mechanism of enzymatic dismutation of superoxide anion-radicals |
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| Authors: | Kornienko I V Kletskiĭ M E Kornienko I E Vnukov V V Vodolazhskiĭ D I |
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| Affiliation: | Central Forensic Identification Laboratory, Ministry of Defense of the Russian Federation, ul. Lermontovskaya 60, Rostov-na-Donu, 344010 Russia. |
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| Abstract: | The mechanism of interaction of the superoxide radical O2-. with lysine was studied by the methods of polarography and ab initio quantum chemical calculations. It was shown that O2-. interacts with lysine to form a thermodynamically stable complex with proton transfer and formation of the HO2. radical. |
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