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Efficient Perovskite Photovoltaic‐Thermoelectric Hybrid Device
Authors:Ling Xu  Yan Xiong  Anyi Mei  Yue Hu  Yaoguang Rong  Yinhua Zhou  Bin Hu  Hongwei Han
Affiliation:Michael Gr?tzel Center for Mesoscopic Solar Cells, Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, China
Abstract:An efficient perovskite photovoltaic‐thermoelectric hybrid device is demonstrated by integrating the hole‐conductor‐free perovskite solar cell based on TiO2/ZrO2/carbon structure and the thermoelectric generator. The whole solar spectrum of AM 1.5 G is fully utilized with the ≈1.55 eV band gap perovskite (5‐AVA)x(MA)1?xPbI3 absorbing the visible light and the carbon back contact absorbing the infrared light. The added thermoelectric generator improves the device performance by converting the thermal energy into electricity via the Seebeck effect. An optimized hybrid device is obtained with a maximum point power output of 20.3% and open‐circuit voltage of 1.29 V under the irradiation of 100 mW cm?2.
Keywords:carbon electrodes  hybrid devices  perovskites  photovoltaics  thermoelectric
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