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Role of gold in a complex cascade reaction involving two electrocyclization steps |
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| Authors: | Jason G Harrison Dean J Tantillo |
| Institution: | 1. Department of Chemistry, University of California–Davis, One Shields Avenue, Davis, CA, 95616, USA |
| Abstract: | Quantum chemical computations (B3LYP/LACVP**) were applied to assess the impact of Au(I) complexation on activation barriers for sequential electrocyclization reactions (one a 1,2-dihydroazete ring-opening and another a pentadienyl cation ring-closure) proposed to occur during a complex reaction cascade that converts alkynes and imines to cyclopentenimines. Gold in a complex cascade reaction |
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