Trace metals in sediments from the humber estuary: A statistical analysis of spatial uniformity |
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Authors: | Alastair Grant Richard Middleton |
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Institution: | (1) School of Environmental Sciences, University of East Anglia, NR4 7TJ Norwich, UK;(2) School of Earth Resources, Hull University, HU6 7RX Hull, UK |
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Abstract: | Concentrations of seven heavy metals (Cu, Zn, Ni, Cr, Nb, Pb, As) in sediments of the Humber estuary and its tributary rivers
have been examined using a variety of statistical methods. Concentrations of metals are rather uniform once the effect of
grain size is adjusted for. This uniformity extends for some distance beyond the turbidity maximum, and in fact well beyond
the normal limit of salt penetration. Detailed statistical analysis of the data do however reveal some trend of concentrations
with position in the estuary, with concentrations of Zn, Ni, and Pb being slightly lower towards the mouth of the estuary.
Nb concentrations are higher near the mouth of the Humber, but this reflects the location of two large discharges of Nb here.
Once these anomalous samples are removed, Nb concentrations are also shown to be spatially homogeneous. The spatial trends
in Zn, Ni and Pb may be due to inputs of very contaminated particulate matter to the upper estuary, to inward transport of
uncontaminated clay particles from the North Sea to the lower estuary or to the exchange of metals between particulate matter
and water. There are however also spatial trends in sediment particle diameter, so some caution needs to be exercised in drawing
conclusions. |
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Keywords: | trace metals distribution grain size adjustment statistical analysis Humber Estuary |
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