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Mechanistic Studies on Thiaminase I : 1. The Stereochemical Course of the Reaction |
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| Authors: | Nicewonger R Rammelsberg A Costello C A Begley T P |
| Abstract: | Thiaminase I catalyzes the displacement of the thiazole moiety of thiamin by a wide variety of nucleophiles. In this paper, we demonstrate that this reaction proceeds with overall retention of stereochemistry. |
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