The Role of Hydrogen from ALD‐Al2O3 in Kesterite Cu2ZnSnS4 Solar Cells: Grain Surface Passivation |
| |
| Authors: | Jongsung Park Jialiang Huang Jaesung Yun Fangyang Liu Zi Ouyang Heng Sun Chang Yan Kaiwen Sun Kyung Kim Jan Seidel Shiyou Chen Martin A Green Xiaojing Hao |
| |
| Institution: | 1. School of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney, NSW, Australia;2. School of Materials Science Engineering, University of New South Wales, Sydney, NSW, Australia;3. School of Information Science & Technology, East China Normal University, Shanghai, China |
| |
| Abstract: | In this research, a new route of surface passivation is reported by introducing hydrogen from the atomic layer deposited (ALD) Al2O3 layer into pure sulfide Cu2ZnSnS4 (CZTS) solar cells. Different amounts of hydrogen are incorporated into the Cu2ZnSnS4/CdS interface through controlling the thickness of the ALD‐Al2O3 layer. The device with three cycles of ALD‐Al2O3 yields the highest efficiency of 8.08% (without antireflection coating) with improved open‐circuit voltage of up to 70 mV. With closer examination on the passivation route of ALD‐Al2O3, it is revealed by the surface chemisty study that the Al2O3 can be etched away by ammonium hydroxide in the CdS buffer deposition process. Instead, the hydrogen is detected within a shallow depth from the CZTS surface, and makes a significant difference in the measured distribution of contact potential difference and device performance. This may be interpreted by the effect of hydrogen passivation of the CZTS surface by curing dangling bonds at the surface of CZTS grains. This work may provide a new direction of further improving the performance of kesterite solar cells. |
| |
| Keywords: | Al2O3 atomic layer deposition Cu2ZnSnS4 hydrogen passivation |
|
|
