Charge Generation and Recombination in an Organic Solar Cell with Low Energetic Offsets

Organic bulk heterojunction (BHJ) solar cells require energetic offsets between the donor and acceptor to obtain high short‐circuit currents (J_SC) and fill factors (FF). However, it is necessary to reduce the energetic offsets to achieve high open‐circuit voltages (V_OC). Recently, reports have highlighted BHJ blends that are pushing at the accepted limits of energetic offsets necessary for high efficiency. Unfortunately, most of these BHJs have modest FF values. How the energetic offset impacts the solar cell characteristics thus remains poorly understood. Here, a comprehensive characterization of the losses in a polymer:fullerene BHJ blend, PIPCP:phenyl‐C61‐butyric acid methyl ester (PC₆₁BM), that achieves a high V_OC (0.9 V) with very low energy losses (E_loss = 0.52 eV) from the energy of absorbed photons, a respectable J_SC (13 mA cm^?2), but a limited FF (54%) is reported. Despite the low energetic offset, the system does not suffer from field‐dependent generation and instead it is characterized by very fast nongeminate recombination and the presence of shallow traps. The charge‐carrier losses are attributed to suboptimal morphology due to high miscibility between PIPCP and PC₆₁BM. These results hold promise that given the appropriate morphology, the J_SC, V_OC, and FF can all be improved, even with very low energetic offsets.