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Uncertainty Analysis and Toxicity Classification in Life-Cycle Assessment Using the Case-study of Gas Purification Systems
Authors:Markus A Meier  Konrad Hungerbühler
Institution:(1) Ciba Specialty Chemicals Inc., K-147.4.39, CH-4002 Basel, Switzerland;(2) Swiss Federal Institute of Technology, Department of Chemical Engineering, Safety and Environmental Technology Group, ETH-Zentrum UNK, CH-8092 Zurich, Switzerland
Abstract:This comprehensive thesis structures the decision-making process for making a choice of the most adequate gas purification system (GasPS). Various gas purification technologies (biofilter, activated carbon filter, catalytic oxidation, thermo-reactor) have been evaluated based on an industrial case-study for waste gas streams. The ecological performance was quantified using the life-cycle impact assessment methods Eco-Indicator 95 and Swiss Ecopoints (environmental scarcities). Both life-cycle impact assessment methods have been improved by a new classification method for volatile organic compounds (VOCs) which considers the environmental fate and exposure as well as the toxicity of these compounds. For life-cycle assessment, a detailed quantitative uncertainty analysis was carried out using Monte Carlo simulation. Based on the uncertainty analysis, developing statements about the significance of the results and of relative differences between various GasPS alternatives has been possible. The eco-efficiency of the investigated GasPSs was finally characterised based on four indicators: Net Ecological Benefit (NEBN), Ecological Yield Efficiency (lgEYE), Net Present Value (NPV), and Ecological-Economic Efficiency (EEE).
Keywords:Chemical industry  clean air legislation  decision-making  eco-efficiency indicators  Eco-Indicator 95  gas purification system  Life-cycle assessment  Swiss Ecopoints  toxic substances  uncertainty analysis
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