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Influence of humic substances on bioavailability of Cu and Zn during sewage sludge composting
Authors:Kang Jun  Zhang Zengqiang  Wang Jim J
Institution:a College of Resources and Environment, Northwest A&F University, Yangling, Shaanxi Province 712100, PR China
b School of Plant, Environmental and Soil Sciences, Louisiana State University Agricultural Center, 104 Sturgis Hall, Baton Rouge, LA 70803, USA
Abstract:Influence of humic substances (HS) on bioavailability of Cu and Zn was characterized during 120 days co-composting of sewage sludge and maize straw. At the initial stage of composting, Cu and Zn in sewage sludge were released as organic matter was degraded, and water soluble Cu and Zn increased markedly. Water soluble Cu and FA content decreased after 21 days whereas water soluble Zn increased during the whole process. Both HA-Cu and HA-Zn were significantly and positively correlated with HA and H/F, respectively. At the end of composting, the distribution coefficients of HA-Cu and HA-Zn reached 27.50% and 3.33% respectively with HA-Cu/HA-Zn ratio increased from 1.29 to 2.73. The results suggest that Cu combined with HA more strongly than Zn, and composting treatment could decrease bioavailability of Cu markedly.
Keywords:Sewage sludge  Composting  Heavy metals  Humic substances  Bioavailability
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