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General occurrence of the glucosinolate glucocochlearin within the Cochlearia genus
Authors:Dauvergne Xavier  Cérantola Stéphane  Salaün Stéphanie  Magné Christian  Kervarec Nelly  Bessières Marie-Anne  Deslandes Eric
Institution:Laboratoire d'Ecophysiologie et de Biotechnologie des Halophytes et des Algues Marines (LEBHAM), EA 3877, Institut Universitaire Européen de la Mer (IUEM), Université de Bretagne Occidentale, F-29280 Plouzané, France. xavier.dauvergne@univ-brest.fr
Abstract:A natural compound, glucocochlearin, was isolated from the aerial parts of 10 different Cochlearia species. The purification of this compound was achieved through HPLC. The identity of the product was established mainly on the basis of spectroscopic NMR (1H, 13C, COSY, TOCSY, HMQC, HMBC, J-MOD) and high resolution mass spectroscopy data. This compound can be considered as a chemomarker of the genus Cochlearia.
Keywords:Cochlearia  Brassicaceae  Glucocochlearin  Electrospray ionisation mass spectrometry (ESIMS)  NMR spectroscopy
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