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Microbial asymmetric oxygenation of an organometallic sulfide |
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| Authors: | Yoshimitsu Yamazaki Kuniaki Hosono |
| Affiliation: | (1) Fermentation Research Institute, AIST, 305 Tsukuba, Ibaraki, Japan |
| Abstract: | Summary Penicillium frequentans IFO 5692 oxidized enantioselectively (methylthiomethyl)ferrocene (1) to (R)-(–)-(methylsulfinylmethyl)ferrocene (2) ( 98 %e.e.) andCorynebacterium equi IFO 3730 to (S)-(+)-2 (69 %e.e.). |
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