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Iron complexes of dioxoborolanylbutadienes |
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| Authors: | Ralf Widmaier John J. Alexander Jeanette A. Krause Bauer Morris Srebnik Guillaume Desurmont Craig A. Homrighausen |
| Affiliation: | a Department of Chemistry, University of Cincinnati, Cincinnati, OH 45221, USA b Department of Chemistry, University of Toledo, Toledo, OH 43606, USA |
| Abstract: | The first [2,3-dialkyl-1,4-bis(1,3-dioxo-4,4,5,5-tetramethyl-2-borolanyl]-1,3-butadiene]Fe(CO)3 complexes (2, alkyl=n-butyl; 3, alkyl=cyclopentyl; 4, ‘alkyl’=phenyl; 5, alkyl=3-chloropropyl) have been prepared from the reaction of bis(cis-cyclooctadiene)Fe(CO)3 (1) with the borolanylbutadienes. The X-ray crystal structures of 2 and 3 are reported. The geometries of the coordinated ligands are compared with those of the free ligands. |
| Keywords: | Borolanylbutadiene complexes Butadiene complexes Iron complexes |
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