The molecular crystal structure and self-assembly behavior of 6(I)-O-(3-nitrophenyl)cyclomaltoheptaose |
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Authors: | Fan Zhi Jing Zuo-Liang Diao Chun-Hua |
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Institution: | College of Sciences, Tianjin University of Science and Technology, Tianjin 300222, PR China. zhifan@public.tpt.tj.cn |
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Abstract: | The mono-modified beta-cyclodextrin derivative, 6(I)-O-(3-nitrophenyl)cyclomaltoheptaose{mono6-O-(3-nitrophenyl)]-beta-cyclodextrin} was synthesized, and its crystal structure was determined by single-crystal X-ray analysis. The crystal structure suggests that the 3-nitrophenyl substituent group is inserted into the adjacent beta-cyclodextrin cavity from the secondary hydroxyl side, and the molecules are stacked along the twofold screw axis to form an infinite one-dimensional polymeric chain. |
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Keywords: | Cyclodextrin Crystal structure Supramolecular chemistry Self-assembly |
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