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Intramolecular photoredox reactions of 1,2-naphthoquinone derivatives
Authors:Yoshio Ando  Fumihiro Wakita  Ken Ohmori  Keisuke Suzuki
Institution:Department of Chemistry, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan
Abstract:Photoirraditation of substituted 1,2-naphthoquinones gives the corresponding oxacycle via intramolecular redox reaction, which enabled net C/>H functionalization of the proximal position to the excited carbonyl group of the quinones. The substrate scope and mechanistic insights are described.</td>
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Keywords:Photoreaction  Redox reaction  1  2-Naphthoquinone  Corresponding authors  
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