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石菖蒲的化学成分研究
引用本文:仝晓刚,程永现. 石菖蒲的化学成分研究[J]. 天然产物研究与开发, 2011, 23(3): 404-409
作者姓名:仝晓刚  程永现
作者单位:1. 中国科学院昆明植物研究所植物化学与西部植物资源持续利用国家重点实验室,昆明,650204;中国科学院研究生院,北京,100049
2. 中国科学院昆明植物研究所植物化学与西部植物资源持续利用国家重点实验室,昆明,650204
基金项目:中国科学院知识创新重要方向项目,中国科学院昆明植物研究所植物化学与西部植物资源持续利用国家重点实验室自主课题项目,云南省中青年学术技术带头人与后备人才项目,国家十一五科技部重大新药创制项目
摘    要:运用色谱法从石菖蒲根茎提取物中分离得到18个化合物,经波谱学分析鉴定为:(7S,8R)-4,9’-di-hydroxyl-3,3’-dimethoxyl-7,8-dihydrobenzofuran-1’-propylneolignan(1),(7S,8R)-4,9’-dihydroxyl-3,3’-dimethoxyl-7,8-dihydrobenzofuran-1’-propylneoligan-9-O-β-D-glucopyranoside(2),7’-hydroxylariciresinol-9-acetate(3),5-羟基-3,7,4’-三甲氧基黄酮(4),野漆树苷(5),紫云英苷(6),松属素-3-O-芸香糖苷(7),山奈酚-3-O-芸香糖苷(8),德钦红景天苷(9),isoschaftoside(10),5-羟甲基糠醛(11),反式桂皮酸(12),3,7-dihydroxy-11,15,23-trioxo-lanost-8,16-dien-26-oicacid(13),3,7-dihydroxy-11,15,23-trioxo-lanost-8,16-dien-26-oic acid methyl ester(14),环阿屯醇(15),胡萝卜苷(16),羽扇豆醇(17),(22E,24R)-ergosta-5,7,22-trien-3β-ol(18)。除化合物4、11和16外,其余15个化合物均为首次从该植物中分离得到。

关 键 词:石菖蒲  天南星科  酚性成分  三萜

Chemical Constituents from Acorus tatarinowii
TONG Xiao-gang,CHENG Yong-xian. Chemical Constituents from Acorus tatarinowii[J]. Natural Product Research and Development, 2011, 23(3): 404-409
Authors:TONG Xiao-gang  CHENG Yong-xian
Affiliation:TONG Xiao-gang1,2,CHENG Yong-xian1 1State Key Laboratory of Phytochemistry and Plant Resources in West China,Kunming Institute of Botany,The Chinese Academy of Sciences,Kunming 650204,China,2Graduate School of the Chinese Academy of Sciences,Beijing 100049
Abstract:Eighteen compounds were isolated from the rhizome of Acorus tatarinowii.Their structures were identified by spectroscopic data as(7S,8R)-4,9′-dihydroxyl-3,3′-dimethoxyl-7,8-dihydrobenzofuran-1′-propylneolignan(1),(7S,8R)-4,9′-dihydroxyl-3,3′-dimethoxyl-7,8-dihydrobenzofuran-1′-propylneoligan-9-O-β-D-glucopyranoside(2),7′-hydroxylariciresinol-9-acetate(3),5-hydroxy-3,7,4′-trimethoxyflavone(4),rhoifolin(5),astragalin(6),pinocembrin-7-O-rutinoside(7),kaempferol-3-O-rutinoside(8),rhodionin(9),isoschaftoside(10),5-hydroxymethyl-2-furaldehyde(11),trans-cinnamic acid(12),3,7-dihydroxy-11,15,23-trioxo-lanost-8,16-dien-26-oicacid(13),3,7-dihydroxy-11,15,23-trioxo-lanost-8,16-dien-26-oic acid methyl ester(14),cycloartenol(15),daucosterol(16),lupeol(17),(22E,24R)-ergosta-5,7,22-trien-3β-ol(18).Except for compounds 4,11,and 16,all the other substances were obtained from this plant for the first time.
Keywords:Acorus tatarinowii  Araceae  phenols  triterpenoids  
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