Overall view of the use of chiral platinum(II) complexes as chiral derivatizing agents (CDAs) for the enantiodiscrimination of unsaturated compounds by 195Pt NMR |
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| Authors: | Uccello-Barretta Gloria Bernardini Raffaella Balzano Federica Salvadori Piero |
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| Affiliation: | Centro di Studio del CNR per le Macromolecole Stereordinate ed Otticamente Attive, Dipartimento di Chimica e Chimica Industriale, 56126 Pisa-Italy. |
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| Abstract: | The use of organometallic CDAs based on ethene-platinum(II) complexes, covalent cis- and trans-dichloro(Am)(ethylene)platinum(II), and ionic [PtCl(3)(C(2)H(4))](-)[AmH](+), containing primary and secondary amines, for the (195)Pt NMR enantiodiscrimination of chiral unsaturated compounds is reviewed. |
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