Synthesis of both enantiomers of isorobinal,a novel cyclic monoterpene isolated from the astigmatid mite,Rhizoglyphus sp |
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| Authors: | Liang Ting Kuwahara Shigefumi |
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| Affiliation: | Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University, 1-1 Tsutsumidori-Amamiyamachi, Aoba-ku, Sendai 981-8555, Japan. |
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| Abstract: | Both enantiomers of isorobinal, a cyclic monoterpene isolated from the astigmatid mite (Rhizoglyphus sp.), were synthesized from the enantiomers of perillaldehyde in four steps by using PCC-oxidation of a tertiary allylic alcohol intermediate as the key step. |
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