|
|||||
|
|
Phosphite-derivatized ruthenium-carbohydrate complexes in the catalytic hydration of nitriles. short communication |
|
| Authors: | Ashraf Shaheen M Berger Isabella Nazarov Alexey A Hartinger Christian G Koroteev Mikhail P Nifant'ev Eduard E Keppler Bernhard K |
| Institution: | University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna. |
| Abstract: | The synthesis of metal complexes with bioligands is one option to introduce chirally defined ligands to catalysts. Herein, the hydration of nitriles to the corresponding carboxamides by use of ruthenium(II) complexes is described, which were obtained by attaching derivatives of the 3,5,6-bicyclophosphite-alpha-D-glucofuranoside ligand. |
| Keywords: | Catalysis Carbohydrates Acetonitriles chloro‐ Ruthenium complexes Phosphites Hydration |
| 本文献已被 PubMed 等数据库收录！ | |