A new polymorph of dichlorido(1,10-phenanthroline)platinum(II) |
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| Authors: | Carmen R. Barone Giovanni Natile |
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| Affiliation: | Dipartimento Farmaco-Chimico, Università degli Studi di Bari Aldo Moro, via E. Orabona 4, 70125 Bari, Italy |
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| Abstract: | A yet unreported polymorph of [PtCl2(1,10-phenanthroline)] was obtained by slow decomposition, in CH2Cl2 solution, of [Pt{CH2CH2N(CH2CH3)2-κC,κN}(1,10-phenanthroline)](ClO4). The structure of the new orthorhombic form, III, (space group Pna21), is described and compared to those of the two already reported forms, I and II, which are monoclinic (space group P21/c) and orthorhombic (space group Pca21), respectively [21]. Polymorph III appears to be the least stable of the three. |
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| Keywords: | Platinum complexes Polymorphism 1,10-Phenanthroline X-ray crystal structure |
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