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Novel heterometallic palladium-silver complex |
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| Authors: | Natalia Yu Kozitsyna Sergei E Nefedov Alexander A Markov Yuri A Velikodny Tatiana S Zyubina Michael N Vargaftik |
| Institution: | a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation b M.V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation c G.K. Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation d Institute for New Chemical Problems, Russian Academy of Sciences, 142432 Moscow Region, Chernogolovka, Russian Federation |
| Abstract: | The reaction between Pd3(OOCMe)6 and Ag2(OOCMe)2 afforded the first palladium-silver heterometallic acetate-bridged complex PdII(μ-OOCMe)2AgI(HOOCMe)2]2 (1). The molecular geometry and electronic structure of 1 were studied by single-crystal XRD and quantum-chemical DFT calculations. Thermal transformations of 1in vacuo and under Ar, H2 produced PdAg alloy nanoparticles characterized with powder XRD and EXAFS. |
| Keywords: | Palladium Silver Heterometallic complexes X-ray structure Quantum-chemical analysis Thermal decomposition |
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