Three novel coordination networks dependent upon H2btze ligand [H2btze = 1,2-bis(tetrazol-5-yl) ethane] |
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| Authors: | Lei Shen Qiao-Yun Li Xiao-Yan Tang Feng Zhou Zhu-Feng Miao Jian-Ning Jin Wei Shen |
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| Institution: | Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, 215500 Jiangsu, PR China |
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| Abstract: | Three novel metal-organic frameworks, Zn(btze)]n (1), Zn(btze)(H2O)]n (2) and Mn(btze)(H2O)4]n·(H2O)2 (3) btze = 1,2-bis(tetrazol-5-yl) ethane anion], were synthesized and characterized by elemental analysis, IR spectroscopy, X-ray crystallography and thermogravimetric analysis. The crystal structures study reveal that 1 displays a 3D framework, 2 displays a 2D layer structure and 3 displays a 1D polymeric chain. The luminescence properties of 1-3 were investigated at room temperature in solid state. |
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| Keywords: | Crystal structure Zinc Manganese H2btze Luminescence |
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